Category Archives: Hazardous emissions

How industrial hygienists anticipate, recognize, and respond to rail emergencies

From Occupational Health & Safety OHSonline
[Editor:   Most significant: “The U.S. Department of Transportation’s Pipeline and Hazardous Materials Safety Administration recently released a web-accessible Transportation Rail Incident Preparedness and Response training resource.”  – RS

How Industrial Hygienists Assist in Rail Emergencies

Speaking at an AIHce 2016 session, several experts said industrial hygienists are well suited to anticipate, recognize, and respond to the hazards and to control the risks using science-based methods.
By Jerry Laws, Jul 01, 2016

All hazardous material railcarsIndustrial hygienists are well prepared to perform an important role during the response to a railroad hazardous materials emergency, several experienced experts said during an AIHce 2016 session about rail crude oil spills on May 24. Risk assessment, data analysis, and plan preparation (such as the health and safety plan, respiratory protection plan, and air monitoring plan) are important early in the response to such emergency incidents, and CIHs are equipped to do all of these, they stressed.

“With our knowledge, skills, and abilities, the training and education that industrial hygienists get, we’re well prepared” to interpret data on the scope and nature of a hazmat spill following a derailment, said Billy Bullock, CIH, CSP, FAIHA, director of industrial hygiene with CSX Transportation. He mentioned several new roles the industrial hygienist can manage in such a situation: health and safety plan preparation, town hall meetings to inform the public, preparing news releases for area news media, interpreting data from air monitoring, working with the local health department, and serving as the liaison with area hospitals, which can improve their treatment of patients affected by the spill if they understand where exposures really are happening and where a gas plume from the spilled crude is moving, he said.

Bullock said the industrial hygienist’s role is primarily in evaluating chemical exposures:

    • assessing the risk for inhalation hazards
    • supporting operational decisions
    • gathering valid scientific information
    • managing data and ensuring data quality reporting and recordkeeping

“All of these things we do as part of our day job transfer to an emergency situation very, very well,” he said, explaining that it’s very important to gain the trust of local responders and officials, including fire department leaders, hazardous materials response teams, the health department, and city officials.

Another speaker, Laura Weems, CIH, CSP, CHMM, with the U.S. Army Corps of Engineers in Little Rock, Ark., agreed, saying industrial hygienists are well suited to anticipate, recognize, and respond to hazards and to control risks using science-based methods.

Cleanup Workers Face Inhalation, Fire, and Heat Stress Hazards

Scott Skelton, MS, CIH, senior industrial hygienist for CTEH, the Center for Toxicology and Environmental Health, LLC, and other speakers explained that the hazard assessment following a hazmat derailment begins by identifying the type of crude oil that has spilled. It’s critical to know its flammability and the status of the oil’s containment, he said, and if there is an active fire, officials in command of the response will have to decide whether cleanup personnel are wearing flame-resistant clothing or chemical-protective apparel and will default to protecting against the greater hazard, he explained.

Benzene exposure—a dermal and inhalation hazard—is a concern in the early hours of a crude oil spill following the derailment, Skelton said. He discussed a 2015 test spill into a tank measuring 100 feet by 65 feet, where the benzene was completely lost and other lighter compounds also were lost 24 hours after the spill occurred. But that type of large surface area for a crude oil spill is not typical at actual derailments, he said. Still, he said the inhalation risk for cleanup workers is of most concern during the initial 24 hours of a spill.

“It’s my opinion that heat stress is the most dangerous aspect,” Skelton said. “With these [cleanup] guys, heat stress risk is extraordinary.” The American Petroleum Institute (API)’s report on PPE use by workers involved in the cleanup of the Deepwater Horizon oil spill confirmed this, he added.

Patrick Brady, CIH, CSP, general director of hazardous materials safety for BNSF Railway Company, pointed out that crude oil spills from derailments are rare: 99.998 percent of the 1.7 million hazardous materials shipments moved by the railroad during 2015 were completed without an accidental release, he said.

Brady said the railroad pre-positions 253 first responders along with needed cleanup equipment at 60 locations along its rail network. “The best case planning for us is we don’t rely on any local resources to be there at all,” he said, so BNSF hires hazmat contractors for crude oil derailment response and brings in consultants from CTEH to interpret monitoring data. (Responding to a question from someone in the session’s audience, he touted the AskRail™ app, a tool that gives emergency responders information about the hazardous materials inside a railcar or the contents being transported on an entire train. http://www.askrail.us/)

Dyron Hamlin, MS, PE, a chemical engineer with GHD, said hydrogen sulfide is the primary acute hazard faced by responders after a spill occurs. While an H2S concentration below 50 ppm is irritating, 50-100 ppm causes loss of the individual’s sense of smell, and 100 ppm is immediately dangerous to life and health. If the crude oil in a railcar has 1 percent sulfur in the liquid, GHD personnel typically measure 300 ppm of H2S in the headspace inside the railcar, Hamlin said.

Echoing Skelton’s comments, Hamlin said API found that 50 percent of the mass of typical crude oils is lost in the first 48 hours following a spill; following the Deepwater Horizon spill, the volatile organic compounds measured in the air during the response were lower than expected because of water dissolution in the Gulf of Mexico, he said.

He cautioned the audience members to keep in mind that all hazardous material railcars’ contents are mixtures, which complicates the task of calculating boiling points and other factors important to responders and cleanup workers.

DOT Helps Out PHMSA Offers Rail Incident Training Resource

The U.S. Department of Transportation’s Pipeline and Hazardous Materials Safety Administration recently released a web-accessible Transportation Rail Incident Preparedness and Response training resource, saying it gives emergency responders critical information and best practices related to rail incidents involving Hazard Class 3 Flammable Liquids, such as crude oil and ethanol. It is off-the-shelf training that is available online and can be used anywhere throughout the country.

“TRIPR is the result of a concerted effort between federal agencies and rail safety stakeholders to improve emergency response organizations’ ability to prepare for and respond to rail incidents involving a release of flammable liquids like crude oil or ethanol,” said PHMSA Administrator Marie Therese Dominguez. “We are committed to safety and providing responders with flexible, cost-effective training and resources that help them respond to hazmat incidents safely.” The resource was developed in conjunction with other public safety agencies, such as the Federal Emergency Management Agency, the U.S. Coast Guard, and EPA, in order to prepare first responders to safely manage incidents involving flammable liquids.

“Some of the most important actions we have taken during the last two years to increase the safety of transporting crude oil by rail have been providing more resources, better information, and quality training for first responders. This web-based training is another tool to help first responders in communities large and small, urban and rural, quickly and effectively respond if a derailment happens,” said FRA Administrator Sarah E. Feinberg.

The TRIPR curriculum focuses on key hazmat response functions and incorporates three animated training scenarios and introductory videos to help instructors facilitate tabletop discussions. PHMSA announced that it plans to host a series of open houses nationwide to promote the curriculum. Visit http://dothazmat.vividlms.com/tools.asp to download the TRIPR materials.

About the Author: Jerry Laws is Editor of Occupational Health & Safety magazine, which is owned by 1105 Media Inc.
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    FRACTRACKER ALLIANCE: Who Lives Near the Refineries?

    Repost from FracTracker Alliance

    Petrochemical Industry Presence in East Bay CA’s North Coast Refinery Corridor

    Who Lives Near the Refineries?

    By Kyle Ferrar, Western Program Coordinator & Kirk Jalbert, Manager of Community-Based Research & Engagement, March 30, 2016

    Key Takeaways

    • Communities living along the North Coast of the East Bay region in California are the most impacted by the presence of the petrochemical industry in their communities.
    • Emissions from these facilities disproportionately degrade air quality in this corridor region putting residents at an elevated risk of cancer and other health impacts.
    • People of color are more likely to live near the refineries and are therefore disproportionately affected.

    Refinery Corridor Introduction

    The North Coast of California’s East Bay region hosts a variety of heavy industries, including petroleum refineries, multiple power plants and stations, chemical manufacturing plants, and hazardous waste treatment and disposal facilities. Nationwide, the majority of petroleum refineries are located in heavily industrialized areas or near crude oil sources. The north coast region is unique. Access to shipping channels and the location being central to the raw crude product from North Dakota and Canada to the North, and California’s central valley oil fields to the south has resulted in the development of a concentrated petrochemical infrastructure within the largely residential Bay Area. The region’s petrochemical development includes seven fossil fuel utility power stations that produce a total of 4,283 MW, five major oil refineries operated by Chevron, Phillips 66, Shell Martinez, Tesoro, and Valero, and 4 major chemical manufacturers operated by Shell, General Chemical, DOW, and Hasa Inc. This unequal presence has earned the region the title, “refinery corridor” as well as “sacrifice zone” as described by the Bay Area Refinery Corridor Coalition.

    The hazardous emissions from refineries and other industrial sites are known to degrade local air quality. It is therefore important to identify and characterize the communities that are affected, as well as identify where sensitive populations are located. The communities living near these facilities are therefore at an elevated risk of exposure to a variety of chemical emissions. In this particular North Coast region, the high density of these industrial point sources of air pollution drives the risk of resultant health impacts. According to the U.S.EPA, people of color are twice as likely to live near refineries throughout the U.S. This analysis by FracTracker will consider the community demographics and other sensitive receptors near refineries along the north coast corridor.

    In the map below (Figure 1) U.S. EPA risk data in CalEnviroscreen is mapped for the region of concern. The map shows the risk resulting specifically from industrial point sources. Risk along the North Coast is elevated significantly. Risk factors calculated for the region show that these communities are elevated above the average. The locations of industrial sites are also mapped, with specific focus on the boundaries or fencelines of petrochemical sites. Additional hazardous sites that represent the industrial footprint in the region have been added to the map including sites registered with Toxic Release Inventory (TRI) permits as well as Superfund and other Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) sites. The Toxmap TRI sites are facilities that require a permit to emit hazardous air pollutants. The superfund and other CERCLA sites are locations where a historical footprint of industry has resulted in contamination. The sites are typically abandoned or uncontrolled hazardous waste sites that are part of register for tax-funded clean-ups.

    Figure 1. Interactive map of risk in the East Bay’s North Coast refinery corridor

    View Map Fullscreen | How Our Maps Work

    Oil refineries in particular are unique sources of air emissions. There are 150 large domestic refineries throughout the United States. They are shown in the map in Figure 2 below. The majority (90%) of the refined products from these refineries are fuels; motor vehicle gasoline accounts for 40%. The refinery sites have hundreds of stacks, or point sources, and they emit a wide variety of pollutants, as outlined by the U.S. EPA:

    • Criteria Air Pollutants (CAPs)
      • Sulfur Dioxide (SO2)
      • Nitrogen Oxides (NOx)
      • Carbon Monoxide (CO)
      • Particulate Matter (PM)
    • Volatile Organic Compounds (VOCs)
    • Hazardous Air Pollutants (HAPs)
      • Carcinogens, including benzene, naphthalene, 1,3-butadiene, PAH
      • Non-carcinogenic HAP, including HF and HCN
      • Persistent bioaccumulative HAP, including mercury and nickel
    • Greenhouse Gases (GHG)
    • Hydrogen Sulfide (H2S)

    Figure 2. Map of North American Petroleum Refineries


    View Map Fullscreen | How Our Maps Work

    BAAQMD Emissions Index

    Disparate health impacts are therefore a known burden for these Bay Area communities. The region includes the cities of Richmond, Pinole, Hercules, Rodeo, Crockett, Port Costa, Benicia, Martinez, Mt. View, Pacheco, Vine Hill, Clyde, Concord, Bay Point, Antioch, and Oakley. In addition to preserving the ecological system health of this intercostal region is also important for both the ecological biodiversity of the marsh as well as commercial and recreational purposes. These wetlands provide a buffer, able to absorb rising waters and abate flooding.

    The Bay Area Air Quality Management District’s (BAAQMDCumulative Impacts report identified areas where air pollution’s health impacts are relatively high in the San Francisco Bay Area. The report is does not limit their analysis to the North Coast, but shows that these regions with the most impacts are also the most vulnerable due to income, education level, and race and ethnicity. The report shows that there is a clear correlation between socio-economic disadvantages and racial minorities and the impacted communities. Figure 3 shows the regions identified by the BAAQMD as having the highest pollution indices.

    Analysis

    This analysis by FracTracker focuses specifically on the north shore of the East Bay region. Like the BAAQMD report, National Air toxic Assessment (NATA) data to identify census tracts with elevated risk. Specifically, elevated cancer and non-cancer risk from point sources emitting hazardous air pollutants (HAPs) as regulated by the U.S. EPA were used. CalEnviroScreen 2.0 data layers were also incorporated, specifically the U.S. EPA’s Risk Screening Environmental Indicators (RSEI) data. RSEI uses toxic release inventory (TRI) data, emission locations and weather to model how chemicals spread in the air (in 810m-square grid units), and combines air concentrations with toxicity factors.

    The census tracts that were identified as disproportionately impacted by air quality are shown in the map below (Figure 4). The demographics data for these census tracts are presented in the tables below. Demographics were taken from the U.S. census bureau’s 2010 Census Summary File 1 Demographic Profile (DP1). The census tracts shapefiles were downloaded from here.

    Figure 4. Interactive Map of Petrochemical Sites and Neighboring Communities in the East Bays North Coast Industrial Corridor

    View Map Fullscreen | How Our Maps Work

    Buffers were created at 1,000 ft; 2,000 ft; and 3,000 ft buffers from petrochemical sites. These distances were developed as part of a hazard screening protocol by researchers at the California Air Resources Board (ARB) to assess environmental justice impacts. The distances are based on environmental justice literature, ARB land use guidelines, and state data on environmental disamenities (Sadd et al. 2011). A demographical profile was summarized for the population living within a distance of 3,000 feet, and for the census tracts identified as impacted by local point sources in this region. The analysis is summarized in Table 1 below. Additional data on the socioeconomic status of the census tracts is found in Table 2.

    Based on the increased percentage of minorities and indicators of economic hardship shows that the region within the buffers and the impacted census tracts host a disproportionate percentage of vulnerable populations. Of particular note is 30% increase in Non-white individuals compared to the rest of the state. We see in Table 2 that this is disparity is specifically for Black or African American communities, with an over 150% increase compared to the total state population. The number of households reported to be in poverty in the last 12 months of 2014 and those households receiving economic support via EBT are also elevated in this region. Additional GIS analysis shows that 7 healthcare facilities, 7 residential elderly care facilities, 32 licensed daycares, and 17 schools where a total of 10,474 students attended class in 2014. Of those students, 54.5% were Hispanic and over 84% identified as “Non-white.”

    Table 1. Demographic Summaries of Race. Data within the 3,000 ft buffer of petrochemical sites was aggregated at the census block level.

    Total Population Non-White Non-White (%ile)  Hispanic or Latino  Hispanic or Latino (%ile)
    Impacted Census Tracts 387,446 212,307 0.548 138,660 0.358
    3,000 ft. Buffer 77,345 41,696 0.539 30,335 0.392
    State Total 37,253,956 0.424 0.376

    Table 2. Additional Status Indicators taken from the 2010 census at the census tract level

    Indicators (Census Tract data) Impacted Count Impacted Percentile State Percentile
    Children, Age under 5 27,854 0.072 0.068
    Black or African American 60,624 0.156 0.062
    Food Stamps (households) 0.1103 0.0874
    Poverty (households) 0.1523 0.1453

    Conclusion

    The results of the refinery corridor analysis show that the communities living along the North Coast of the East Bay region are the most impacted by the presence of the petrochemical industry in their communities. Emissions from these facilities disproportionately degrade air quality in this corridor region putting residents at an elevated risk of cancer and other health impacts. The communities in this region are a mix of urban and single family homes with residential land zoning bordering directly on heavy industry zoning and land use. The concentration of industry in this regions places an unfair burden on these communities. While all of California benefits from the use of fossil fuels for transportation and hydrocarbon products such as plastics, the residents in this region bear the burden of elevated cancer and non-cancer health impacts.

    Additionally, the community profile is such that residents have a slightly elevated sensitivity when compared to the rest of the state. The proportion of the population that is made up of more sensitive receptors is slightly increased. The region has suburban population densities and more children under the age of 5 than average. The number of people of color living in these communities is elevated compared to background (all of California). The largest disparity is for Black or African American residents. There are also a large number of schools located within 3,000 ft of at least one petrochemical site, where over half the students are Hispanic and the vast majority are students of color. Overall, people of color are disproportionately affected by the presence of the petrochemical industry in this region. Continued operation and any increases in production of the refineries in the East Bay disproportionately impact the disadvantaged and disenfranchised.

    With this information, FracTracker will be elaborating on the work within these communities with additional analyses. Future work includes a more in depth look at emissions and drivers of risk on the region, mapping crude by rail terminals, and working with the community to investigate specific health endpoints. Check back soon.

    References

    1. U.S.EPA. 2011. Addressing Air Emissions from the Petroleum REfinery Sector U.S. EPA. Accessed 3/15/16.
    2. Sadd et al. 2011. Playing It Safe: Assessing Cumulative Impact and Social Vulnerability through an Environmental Justice Screening Method in the South Coast Air Basin, California. International Journal of Environmental Research and Public Health. 2011;8(5):1441-1459. doi:10.3390/ijerph8051441.

    ** Feature image of the Richmond Chevron Refinery courtesy of Paul Chinn | The Chronicle

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