Category Archives: Particulate pollution

Massive Fire & Explosion Today at Texas Petroleum Processing Plant: ‘Effects of the Chemical in the Air Are Unknown’

[Note from BenIndy: It is fascinating how hard it is to find and pin down good coverage of industrial accidents – especially refinery fires, plant explosions, and so on – when they occur in Texas. We have Common Dreams and ABC13/KTRK in Texas to thank for their coverage today. Perhaps more information about the source of the fire, the danger the toxic smoke and particles in the air in Shepherd may pose, and any additional impacts will be made more available tomorrow. From one refinery town to another, Benicia surely sends Shepherd its heartfelt hopes for a speedy recovery for the town, a thorough investigation of the root causes for this absolutely heinous disaster, and the creation of additional protections for the safety and health of its residents.]

Aerial view of chemical fire in Shepherd, Texas on November 8, 2023. | Fox News 26 / Screenshot.

The explosion resulted in a massive fire as residents in and around the town of Shepherd were ordered to stay inside and turn off their HVAC systems to avoid contact with the toxic smoke and particles in the air.

Common Dreams, by Common Dreams Staff, November 8, 2023

At least one worker was reported injured and the surrounding community placed under a shelter-in-place order after an explosion at a chemical plant in the town of Shepherd, Texas on Wednesday resulted in a monstrous and toxic fire.

Roughly 60 miles north of Houston in Jacinto County, the explosion and subsequent chemical blaze took place at the Sound Resource Solutions facility, a petroleum processing plant. A source told ABC 13 News that a 1,000-gallon propane tank sits in the middle of the fire while various highly flammable toxic chemicals and materials are used at the plant.

“Polk County Emergency Management recommends that residents along US Hwy 59 from Goodrich to Leggett shelter-in-place and turn off HVAC systems in homes and businesses immediately,” said a local emergency response from officials in neighboring Polk County. “At this time, the effects of the chemical in the air are unknown.”

According to the Sound Resource Solutions website, the chemical products and solvents used or generated at the processing plant include: xylene, toluene, acetone, methy ethyl ketone, phosphoric acid, acetic acid, sulfuric acid 93, various isoproply alcohols, hexan, and others.

Local affiliate Fox 26 was providing live coverage:

There is no confirmed information about the cause of the fire, though some local outlets reported talking with workers who said a forklift accident may have been the initial cause that set off a larger chain reaction.

Air pollution linked to rise in antibiotic resistance that imperils human health

[Note from BenIndy Contributor Nathalie Christian: Air pollution and climate change’s impact on public health is so much varied and vast than a lot of people realize. Self included.]

Global study suggests connection has been strengthened over time across every country and continent.

The Guardian, by Andrew Gregory, August 7, 2023

Air pollution is helping to drive a rise in antibiotic resistance that poses a significant threat to human health worldwide, a global study suggests.

The analysis, using data from more than 100 countries spanning nearly two decades, indicates that increased air pollution is linked with rising antibiotic resistance across every country and continent.

It also suggests the link between the two has strengthened over time, with increases in air pollution levels coinciding with larger rises in antibiotic resistance.

“Our analysis presents strong evidence that increasing levels of air pollution are associated with increased risk of antibiotic resistance,” researchers from China and the UK wrote. “This analysis is the first to show how air pollution affects antibiotic resistance globally.” Their findings are published in the Lancet Planetary Health journal.

Antibiotic resistance is one of the fastest-growing threats to global health. It can affect people of any age in any country and is already killing 1.3 million people a year, according to estimates.

The main drivers are still the misuse and overuse of antibiotics, which are used to treat infections. But the study suggests the problem is being worsened by rising levels of air pollution.

The study did not look at the science of why the two might be linked. Evidence suggests that particulate matter PM2.5 can contain antibiotic-resistant bacteria and resistance genes, which may be transferred between environments and inhaled directly by humans, the authors said.

Air pollution is already the single largest environmental risk to public health. Long-term exposure to air pollution is associated with chronic conditions such as heart disease, asthma and lung cancer, reducing life expectancy.

Short-term exposure to high pollution levels can cause coughing, wheezing and asthma attacks, and is leading to increased hospital and GP attendances worldwide.

Curbing air pollution could help reduce antibiotic resistance, according to the study, the first in-depth global analysis of possible links between the two. It also said that controlling air pollution could greatly reduce deaths and economic costs stemming from antibiotic-resistant infections.

The lead author, Prof Hong Chen of Zhejiang University in China, said: “Antibiotic resistance and air pollution are each in their own right among the greatest threats to global health.

“Until now, we didn’t have a clear picture of the possible links between the two, but this work suggests the benefits of controlling air pollution could be twofold: not only will it reduce the harmful effects of poor air quality, it could also play a major role in combatting the rise and spread of antibiotic-resistant bacteria.”

Although air is recognised as being a direct pathway for disseminating antibiotic resistance, there is limited data on the different pathways that antibiotic resistant genes are carried via air pollution.

Potential pathways include hospitals, farms and sewage-treatment facilities that emit and spread antibiotic-resistant particles through the air and then across wide distances.

Until now, there was limited data on how much influence PM2.5 air pollution – which is made up of particles 30 times smaller than the width of a human hair – has on antibiotic resistance globally.

Sources of PM2.5 include road traffic, industrial processes and domestic coal and wood burning. Data indicates 7.3 billion people globally are directly exposed to unsafe average annual PM2.5 levels.

The authors created an extensive dataset to explore whether PM2.5 was a key factor driving global antibiotic resistance, using data for 116 countries from 2000 to 2018. The data sources included the World Health Organization, European Environment Agency and the World Bank.

The findings indicate antibiotic resistance increases with PM2.5, with every 10% rise in air pollution linked with increases in antibiotic resistance of 1.1%.  

The association has strengthened over time, with changes in PM2.5 levels leading to larger increases in antibiotic resistance in more recent years. The analysis indicates antibiotic resistance resulting from air pollution was linked to an estimated 480,000 premature deaths in 2018.

A modelling of possible future scenarios indicates that if there were no changes to current policies on air pollution, by 2050 levels of antibiotic resistance worldwide could increase by 17%. The annual premature death toll linked to antibiotic resistance could rise to about 840,000. [Emph. added by BenIndy Contributor.]

The authors acknowledged limitations to their study. A lack of data in some countries may have affected the overall analysis, they said.

The study was observational, so could not prove cause and effect. Future research should focus on investigating the underlying mechanism of how air pollution affects antibiotic resistance, they said.

A second study published in the journal BMJ Mental Health found that exposure to relatively high levels of air pollution was associated with increased use of community mental health services by people with dementia. The long-term study focused on a large area of London with heavy traffic.

Cracking Down on Refinery Emissions – all about “cat crackers”

[See also: Baykeeper notice of intent to sue Amports; Video and photos at Port of Benicia show fossil fuel polluter in the act;  Marilyn Bardet – Petcoke pollution in Benicia, photos going back to 1995]

A “cat cracker” may sound like a child’s snack, but…

Shell refinery in Martinez. Wikimedia Commons
Bay Area Monitor, League of Women Voters Bay Area, by Leslie Stewart, June-July 2021

A “cat cracker” may sound like a child’s snack, but call it by its full name — fluidized catalytic cracking unit — and it is obviously something far different. Cat crackers are a central piece of refinery equipment that turns crude oil into gasoline, diesel and aviation fuel. Regulating this specialized equipment, referred to by the acronym FCCU, recently resulted in unusually high public participation in a significant Bay Area Air Quality Management District decision.

Reducing pollution is challenging for refineries. Crude oil is a complex mixture of hydrocarbons, which is why it can be split into other products. In addition, it usually contains varying amounts of sulfur, nitrogen, oxygen and various metals, so refining it generates toxic compounds and particles which must be controlled. Refineries are subject to a multitude of regulations to prevent pollution reaching the environment and affecting the community.

FCCUs are responsible for over 50 percent of the particulate matter from refineries — over 800 tons per year — and 17% of particles 10 microns or less in diameter (PM10) from facilities with Air District permits in the region. The Air District’s Rule 6-5, regulating FCCUs in the Bay Area, was first adopted in 2015, because improved federal testing methods showed “scrubbed” FCCU emissions combining with the atmosphere when released to form more particulates than previously thought.  Particulate matter often doesn’t travel far and therefore has its greatest impact on adjacent, disadvantaged communities. Janet Hashe from Atchison Village near the Chevron refinery told the Air District Board in June, “The effects of air pollution are disproportionate on these communities and have been for decades. . .”

Under a recent state law, the Air District must require the Best Available Retrofit Control Technology for pollution sources at facilities that impact disadvantaged communities.  Rule 6-5 was revised in July in accordance with this law.  It will affect up to three of the region’s five refineries: Chevron, PBF (formerly Shell) and the currently inactive Marathon. Phillips 66 doesn’t use an FCCU at its Bay Area facility, and Valero recently installed a wet gas scrubber which should enable it to comply with the updated regulation.

Rule 6-5 now requires refineries to meet more stringent standards for emissions of sulfur dioxide and ammonia. It also sets a new limit on PM10 to reduce these emissions by over 400 tons/year. An agency staff report advised the Board that to reach that standard, local refineries will probably need to use wet gas scrubbers. This technology is used in other refineries across the country in addition to Valero.

The extensive debate over the draft rule, which started in 2019, also considered a more lenient standard that would allow twice as much PM10. Refineries might be able to meet that lower standard with less expensive electrostatic precipitators. During the multiple workshops and detailed discussion by the agency’s staff and Board subcommittees prior to two lengthy Board hearings, the two alternatives were nicknamed .10 and .20, based on the technical definition of how the PM10 output is measured, with .10 being the most stringent. They were also referred to as the ESP (electrostatic precipitator) and WGS (wet gas scrubber) alternatives.

Refinery in Martinez. Wikimedia Commons.

The more lenient .20 standard was potentially easier to achieve, and would have gone into effect by January 2023, while the adopted .10 standard won’t go into effect until January 2026. Although it will take longer to affect the region’s environmental quality, the long-term impact will be greater. Staff estimates show a yearly health benefit in reduced deaths, respiratory disease and cardiac illness of approximately $26-60 million, while the rejected alternative would have achieved only $17-38 million.

Long-term health benefits were the deciding factor for the district’s Stationary Source and Climate Impacts Committee when it voted to send the .10 alternative to the board as the recommended update to the rule. Health effects were also cited by a majority of the organizations and individuals who supported the more stringent alternative during board hearings. As Sally Tobin from Richmond noted at the six-hour June hearing, “Richmond children are hospitalized for asthma twice as often those in other parts of Contra Costa.” The Sierra Club’s Jacob Klein echoed this, saying, “We are learning more and more about the toxic impacts of particulate matter and the environmental racism associated with these emissions.”

However, the .20 limit also had substantial support. A consultant’s report on socioeconomic impacts, prepared as part of the agency’s staff report, concluded that the costs of the .10 limit might result in either employee cutbacks or an increase in gasoline prices, or both. Closures were seen as unlikely, and some public comments suggested that market factors would be the determinant in any decision to shutter a facility. However, refinery workers and their unions agreed with refinery concerns about impacts. Chad Fugate, a third-generation steamfitter, wrote, “We need these refineries to stay open and not run out of town”, while David Akeson was worried that refinery staffing decisions would affect safety, writing, “The recent Chevron fire is still fresh in my mind which was the result of repeat deferral on maintenance due to cost saving.”

District board members were also quite concerned about additional water that would be used in wet gas scrubbers, although reclaimed water and better technology could reduce that impact. Ultimately, they determined that the refinery costs and water usage were substantial unmitigated impacts that were necessary to achieve the benefits of the revised regulation.

Not surprisingly, considering the objections, the Air District has been sued by the two active refineries which will need to upgrade, PBF and Chevron. PBF is already implementing different particulate reduction measures, and maintains that it can’t afford to comply so will shut down. Chevron contests the Air District’s cost-benefit calculations. Both are asking that the rule be set aside; a decision will take several years. Nevertheless, Valero’s improved technology and the switch to refining renewable fuels at Phillips 66, and potentially at Marathon, may indicate the ultimate direction for Bay Area refineries.

Shell hit with $433,000 penalty for emission violations at Martinez refinery

Company cited for 44 infractions between 2017 and 2019

The Shell refinery is seen from Pacheco Boulevard in Martinez, Calif., on Friday, Aug. 10, 2012. (Jane Tyska/Bay Area News Group Archives)

Mercury News, by Shomik Mukherjee, October 15, 2021

MARTINEZ — Shell Oil has agreed to pay air quality regulators a $433,000 penalty for dozens of environmental violations at the oil refinery it once operated.

The refinery amassed 44 violations between 2017 and 2019, largely for emitting excessive amounts of pollutants that studies have shown to cause long-term health problems.

PBF Energy acquired the refinery from Shell in 2019 for $1 billion.

It’s the second settlement reached in a month involving environmental violations at one of Martinez’s two oil refineries. Marathon Petroleum agreed last month to pay $2 million to the Bay Area Air Quality Management District over violations at its now idled Martinez oil refinery, previously operated by oil company Tesoro.

Earlier this year, the air quality district voted to require refineries to dramatically reduce air pollution by upgrading their technology.

The latest settlement will pay for future inspections and enforcement of environmental regulations, the air quality district said.

“Ensuring that we all have clean air to breathe is the Air District’s top priority,” Jack Broadbent, the district’s executive officer, said in a written a statement. “This settlement is one way we hold Shell Oil accountable for its violations of air quality regulations and continue to safeguard clean air for all Bay Area residents.”

Joanne Fanucchi of Pittsburg, is photographed holding a Peoples’ Climate March sign with the Shell refinery in the background in Martinez, Calif., on Friday, April 21, 2017. (Doug Duran/Bay Area News Group) 

The refinery’s former management was found to have improperly monitored the facility’s flare pilots, which burn gas at low amounts to keep the flare system running correctly.

Once the pilots were extinguished, the refinery began emitting excess amounts of harmful pollutants, including hydrogen sulfide and sulfur dioxide, according to the air quality district.

The refinery was also flagged for not correctly sealing its storage tanks, as well as for failing to report violations and keep records up to date.

All the infractions have since been corrected, the air quality district said. An analysis earlier this year by district staff estimated that PBF’s emissions were responsible for six premature deaths each year.

Although East Bay oil refineries historically have employed a lot of people, recent brushes with environmental regulations have thrown their future into question.

PBF Energy, which acquired the Martinez refinery from Shell, warned earlier this year that the costs of cutting emissions by 70% — as required by the air quality district — will force it to shut down the refinery. Chevron, which owns a refinery in Richmond, also pushed back against the mandate.

Meanwhile, the Marathon-owned Golden Eagle Refinery in Martinez is no longer in operation. According to Marathon, the refinery is being transitioned into a facility that will produce fuels that emit less carbon than petroleum diesel.