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Multiple detailed analyses: Bakken crude has high levels of volatile organic compounds and alkane gases

Repost from Salon

Why oil-by-rail is an explosive disaster waiting to happen

A recent spate of fiery train accidents all have one thing in common: highly volatile cargo from North Dakota
Lindsay Abrams  |  May 7, 2014
 Why oil-by-rail is an explosive disaster waiting to happenSeveral CSX tanker cars carrying crude oil in flames after derailing in downtown Lynchburg, Va., Wednesday, April 30, 2014. (Credit: AP/Luann Hunt)

In case the near continuous reports of fiery, deadly oil train accidents hasn’t been enough to convince you, Earth Island Journal is out with a startling investigative piece on North Dakota’s oil boom and the dire need for regulations governing that oil’s transport by rail.

The article is pegged to the train that derailed and exploded last summer in Quebec, killing 47 people, although it just as well could have been the story of the train that derailed and exploded in Alabama last November, the train that derailed and exploded in North Dakota last December, the train that derailed and exploded in Virginia last week or — let’s face it — any future accidents that many see as an inevitability.

The Bakken oil fields in North Dakota are producing over a million barrels of crude oil a day, more than 60 percent of which is shipped by rail. All that greenhouse gas-emitting fossil fuel is bad enough; that more oil spilled in rail accidents last year than the past 35 years combined is also no small thing. But the particular chemical composition of Bakken oil lends an extra weight to these concerns: according to the Pipeline and Hazardous Materials Safety Administration, it may be more flammable and explosive than traditional crude.

The industry denies that there’s anything special about Bakken crude, but Scott Smith, a researcher at the nonprofit group Water Defense, has evidence to the contrary. From Earth Island Journal:

Smith now has conducted detailed analyses of Bakken crude from the three accident sites in Quebec, North Dakota, and Alabama, along with baseline data. He says he is the only outside expert to have done so and has shared those lab results with Earth Island Journal. Even government agencies – including the US Department of Transportation (DOT), which is tasked with regulating oil by rail transport – have been largely kept in the dark about the qualities that make Bakken crude so volatile as well as how it varies throughout the formation. “Despite the energy industry making assurances to DOT more than two months ago, we still lack data we requested and that energy stakeholders agreed to produce,” a Department of Transportation spokesperson told Reuters in March.

All the samples collected and tested by Smith share the same high levels of VOCs [volatile organic compounds] and alkane gases in what Smith says are exceptional combinations. According to Smith, 30 to 40 percent of Bakken crude is made up of toxic and explosive gases. Typically these gases are separated out of the crude oil before transport. A recent report by the Pulitzer Prize-winning website Inside Climate News speculates that because of the whirlwind pace of production in North Dakota and the absence of processing facilities, volatile gases like propane are not being removed at the wellhead.

There’s still a lot we don’t know about Bakken crude, Smith says. This includes the presence of metals, radioactive materials, and gases. Because of the varying depths of the Bakken formation, two wells a mile apart can produce crude oil with very different characteristics. This makes sampling and testing especially tricky. It also makes industry cooperation essential.

Smith still has vials of Bakken crude that he pumped out of the ground nearly a year ago. “When it gets above 80 degrees and you shake them,” he says, “it bends the top of the container. Any form of static electricity will ignite this stuff and blow it up.”

Independent reviews corroborate Smith’s findings. Chemists with California’s Office of Spill Prevention and Response examined Smith’s samples and concluded that the Bakken crude “resembles a typical crude oil that has been mixed with diesel or a diesel/gasoline mix. … Obviously, flammability and volatility are greater concerns with Bakken than with ‘typical’ heavier crudes.” In February The Wall Street Journal, based on its own analysis of data collected by the Capline Pipeline in Louisiana, reported that oil coming from the Bakken has significantly more combustible gases and a higher vapor pressure than oil from other formations. In early March, Canada’s Transportation Safety Board (TSB) issued its own findings from oil samples taken from the nine tank cars that did not derail in Lac-Mégantic. While the TSB does not contend, as Smith does, that the Bakken oil is significantly different from other light sweet crudes, the agency also found that oil coming out of the Bakken has a very low flashpoint – which means that it ignites easily or at a relatively low temperature – a level more similar to unleaded gasoline. When the rail cars went off the track in Lac-Mégantic, sending up sparks and static charges, it didn’t take much to set off explosions. “All of the conditions required for ignition to occur were present,” the TSB report concluded.

It’s a frightening warning worth repeating: without heightened safety standards and federal oversight, the many cities and communities through which trains carting Bakken crude pass are helpless in the face of a potential disaster. “I live in fear of waking up to a bunch of text messages and emails because there’s been a 100-car explosion in Chicago and 300,000 people are vaporized,” Smith said. “Unfortunately, that is a very real possibility if something’s not done.”

Lindsay Abrams is an assistant editor at Salon, focusing on all things sustainable.

The hypocrisy of our our “friendly” giants: Big Oil in our back yards

Repost from The Martinez Gazette
[Editor: The following letter to the editor of The Martinez Gazette comes from our sister city across the Carquinez Strait, but it describes life in every refinery town.  Like Shell Oil, Valero in Benicia does an excellent job of contributing to popular charitable causes here and promotes itself as highly concerned with public health and safety  all the while filling our California skies with pollutants and seeking permission to bring in toxic and dangerous tar-sands and Bakken crudes that lay waste to the earth and its inhabitants from the strip mines and fracking fields all the way to our back door.  – RS]

‘Shell Oil is the hypocrisy at Earth Day’

 May 4, 2014

Dear editor:

Martinez celebrated John Muir’s Birthday and Earth Day last weekend at the John Muir Historical Site. Attendees were offered environmental information from sustainable and recyclable, to energy and water saving to causes of greenhouse gas (GHG) and global warming with the usual sponsors of the IBEW, Republic Services, City of Martinez, and Shell Oil of Martinez.

How does a fossil fuel industry corporation that produces 175 tons of hydrocarbons a day at it’s Martinez Refinery, owns 60 percent of Canadian Boreal Forest that is decimating the ecology to strip mine highly toxic tar sands crude oil to be shipped to its refineries, and has less than 2.5 percent of its overall expenditures in sustainable and renewable energy while totally divesting itself of solar energy and decreasing wind energy interests, get a place at John Muir’s Birthday/ Earth Day event? Certainly, John Muir would have left them off the list.

Shell and Big Oil was the elephant at the party. The Earth Day hypocrisy is that refineries in the Bay Area are the single largest stationary source of volatile organic compounds (VOCs). Shell is responsible for 492 million pounds of VOCs per year. Contra Costa County is the third most toxic county in the state of California. Short term exposure to sulfur dioxide, a refining byproduct, can result in respiratory illness and cardiovascular issues as well as aggravation of asthma. Do you or someone you know have asthma or respiratory illnesses?

There is no spare the air day for Shell or any refinery. When you can’t put a log on the fire, Shell emits over 700,000 tons of hydrocarbons per year, 24 hours a day, seven days a week.

Shell as well as the four other refineries in the Bay Area, are now refining a dirtier crude oil high in sulfur and other metals which emits more hydrocarbons. The tar sand oil from Alberta Canada is heavy like tar and sinks when it hits water, making oil spill recovery impossible. Shell receives this type of crude by ship and a spill of this type while off loading would foul our drinking water in Martinez.

Bakken crude oil, extracted from the Dakotas, is very explosive because of its low flash point and can explode before it is refined. This type of crude is being shipped by rail car through our downtown to the Bay Area refineries and has been in the news recently with train derailments and explosions in Casselton, North Dakota, Louisiana, Lac Megantic Canada and most recently in Lynchburg, Virginia.

The fossil fuel industry is always trying to improve their image within their communities despite their records as gross polluters. Chevron takes a single page ad in the Times every week telling us what a partner they are in the community since sending 15,000 residents to neighboring hospitals after a 2012 fire at their Richmond Refinery. Shell distributed flyers at Earth Day proposing to modernize their Martinez facility by cutting greenhouse gas emissions by 700,000 metric tons a year and reducing water usage by 15 percent. Why did it take them until the Intergovernmental Panel on Climate Change said the fossil fuel industry is the leading contributor of GHG  emissions and a drought in California to get them to start reducing the amount of toxins they emit and the amount of water they use?

If the fossil fuel industry was truly committed to solving the energy issue as it relates to climate change and becoming a leader of green technology, they would not have eliminated wind and solar energy from their repertoire. The easy to extract oil has now been processed and these companies insist on extracting every drop of oil by drilling, hydro fracking, or strip mining to the point where the cost to extract crude oil is equal to the cost to burn it in an efficient engine.

The hypocrisy lies in the fact that Shell Oil made almost $20 billion dollars last year and was awarded the Martinez Business of the Year Award all the while convincing the planners, leaders, and deciders that they are entitled to a seat at the Birthday Party because they put change in the pockets of the community.

Our children and grandchildren are the apples of our eyes and the soft spot in our hearts. Shell Oil knows this and they focus their donations to Martinez Education Foundation, Martinez Unified School District, school scholarships, back packs so our kids can shelter in place, etc… for the children. THIS is the hypocrisy. They contaminate the ground, spew toxics that foul our air, our children’s air: because the money in the community’s pockets makes this poisoning acceptable.

Shell Oil is the Earth Day Hypocrisy.

– James Neu, Martinez

Canada: 3-year phase out or retrofit of DOT-111 tank cars

Repost from Canada’s Financial Post

Canada to phase out in 3 years old rail tankers of type that exploded in Lac-Megantic disaster

Associated Press | April 23, 2014

Smoke rises from railway cars that were carrying crude oil after derailing in downtown Lac-Megantic, Que., July 6, 2013.

Canadian Press – Smoke rises from railway cars that were carrying crude oil after derailing in downtown Lac-Megantic, Que., July 6, 2013.

TORONTO  — Canada will require a three-year phase out or retrofit of the type of rail tankers involved in last summer’s massive explosion of an oil train that destroyed much of a Quebec town and incinerated 47 people, a government official told The Associated Press Wednesday.

Last July, a runaway oil train derailed and exploded in Lac-Megantic, Quebec, near the Maine border. Forty-seven people were incinerated and 30 buildings destroyed.

A government official confirmed the phase out of the DOT-111 tanker cars used to carry oil and other flammable liquids. The official spoke on condition of anonymity because the official was not authorized to speak publicly ahead of the plan’s official announcement.

Canada’s Transport Minister will announce new rules later Wednesday in response to recommendations by Canada’s Transportation Safety Board in the aftermath of the tragedy. U.S. officials will be watching closely as the rail industry is deeply integrated across North America and both nations’ accident investigators implored their governments earlier this year to impose new safety rules.

The DOT-111 tank car is considered the workhorse of the North American fleet and makes up about 70% of all tankers on the rails. But they are prone to rupture. The U.S. NTSB has been urging replacing or retrofitting the tank cars since 1991.

Canada’s safety board has said a long phase-out would not be good enough.

Safety experts have said the soda-can shaped car has a tendency to split open during derailments and other major accidents.

There’s been intense political and public pressure to make oil trains safer since a runaway train with 72 tank cars of North Dakota oil derailed and exploded in Lac-Megantic. The train was left unattended by its lone crew member while parked near the town. The train came loose and sped downhill into Lac-Megantic. More than 60 tank cars derailed and caught fire, and several exploded, destroying much of the downtown.

Oil trains also have exploded and burned in Alabama, North Dakota and New Brunswick in recent months.

The oil industry has been increasingly using trains to transport oil in part because of a lack of pipelines.

U.S. freight railroads transported about 415,000 carloads of crude in 2013, up from just 9,500 in 2008, according to government and industry figures.

The oil trains, some of which are 100 cars long, pass through or near scores of cities and towns.

Some companies have said they will voluntarily take the DOT-111 tank cars offline. Irving Oil Ltd., a large Canadian refiner, has said it will stop using the older DOT-111s by April 30. Canada’s two largest railways, Canadian National Railway and Canadian Pacific Railway, have already said they would move away from the DOT-111. But it is the oil companies or shippers that own or lease many of the cars.

Federal Railroad Administration does not monitor or review railroad emergency response plans

Repost from Environment and Energy Publishing

Oil-by-rail loophole keeps U.S. emergency response plans in the dark

Blake Sobczak, E&E reporter | EnergyWire: Tuesday, April 22, 2014

U.S. transportation officials don’t review how railroads would handle worst-case oil train disasters like last summer’s derailment in Quebec, which killed 47 people in a fiery explosion.

While railroads must keep “basic” emergency response plans in their own files, the Federal Railroad Administration does not monitor or review those plans.

That’s because railroads are required to provide “comprehensive” oil spill response plans to the FRA only if they use tank cars that hold more than 42,000 gallons of crude. In an April 10 letter responding to a Freedom of Information Act request from EnergyWire, FOIA officer Denise Kollehlon said the FRA’s files “do not contain any records related to the active comprehensive ‘oil spill prevention and response plans’ for oil shipments.”

Safety experts and environmentalists say the 42,000-gallon threshold is too high. They stress that the 1996 rule that set the limit never applies in practice. Just five tank cars nationwide are designed to store that much oil in a single packaging, officials say, and the FOIA response confirms that none are hauling crude (EnergyWire, Feb. 19).

The threshold predates the recent surge in oil-by-rail transport, which has seen annual crude shipments jump from fewer than 10,000 carloads in 2008 to 415,000 carloads last year, according to industry data.

Tim Pellerin, fire chief of Rangeley, Maine, said “tangible, realistic” emergency response plans could help firefighters, who often reach remote disaster sites before railroads’ own hazardous materials crews.

“There’s got to be a system in place that checks this and oversees [railroads] to make sure that there are plans in place,” he said in an interview.

Pellerin led a group of U.S. firefighters 60 miles north into Canada after a 72-car oil train derailed and exploded in Lac-Mégantic, Quebec.

The disaster claimed 47 lives and put hazardous materials safety on the map for U.S. and Canadian transportation regulators.

Later derailments and fires in Alabama and North Dakota in the United States and New Brunswick in Canada kept the issue in the spotlight, although they injured no one. Earlier this month, Pellerin called on lawmakers to provide more funding for first responders at a Senate Appropriations subcommittee hearing.

Local fire departments can request hazardous materials shipping and emergency response information from railroads under voluntary industry standards. But picking out potential weak points in such plans “is an awful lot to expect from a small volunteer fire department with a $2,000-per-year budget,” Pellerin said, adding that his department lacks the specialized knowledge needed to gauge the adequacy of railroads’ response measures. “I’m not an expert in 10,000 things — I’m a fire chief,” he said.

The FRA, part of the Department of Transportation, did not respond to requests for comment, although it has previously said it is taking a “comprehensive approach to improving the safe transportation of crude oil by rail.” In February, the regulator reached a voluntary agreement with railroads to tighten oil train operating practices, lowering speed limits through urban areas and committing $5 million in industry funds to prepare first responders, among other measures.

Holly Arthur, spokeswoman for the Association of American Railroads, noted that railroads are also developing an inventory of oil spill emergency response resources under the terms of the agreement.

“This inventory will include locations for the staging of emergency response equipment and, where appropriate, contacts for the notification of communities,” Arthur said in an emailed statement yesterday. “When the inventory is completed [by July 1], railroads will provide DOT with information on the deployment of the resources and make the information available upon request to appropriate emergency responders.”

Emergency response ‘offloaded to local communities’

Safety officials have questioned whether voluntary arrangements go far enough to protect local communities.

Outgoing National Transportation Safety Board Chairwoman Deborah Hersman wrote in a Jan. 23 letter to FRA Administrator Joseph Szabo that without closely regulated response plans, “[rail] carriers have effectively placed the burden of remediating the environmental consequences of an accident on local communities along their routes.”

Hersman reiterated her crude-by-rail concerns yesterday in her farewell address at the National Press Club in Washington, D.C. Crude-by-rail “can be a worst-case-scenario event, and we don’t have provisions in place to deal with it, either on the industry side or for the first responders,” she said.

Experts at the NTSB and Canada’s Transportation Safety Board agree that the magnitude of the Lac-Mégantic disaster swamped the small railroad’s response resources, which can include hazardous materials crews and specialized firefighting foam. The railroad involved in the July 6 crash — Montreal, Maine & Atlantic Railway Ltd. — has since declared bankruptcy in the United States and Canada and is in the process of being taken over by the New York-based Fortress Investment Group (EnergyWire, Jan. 23).

“Railroads have for decades offloaded to local communities the responsibilities for emergency response,” said independent hazardous materials consultant Fred Millar, who has worked with environmental groups including Friends of the Earth.

Millar said he was not surprised by the fact that the FRA does not keep tabs on railroads’ oil spill response plans. “Nobody even has a measure of what would be an adequate emergency response capability,” he said.

By contrast, crude pipelines, storage facilities and waterborne oil tankers must comply with lengthier emergency response requirements laid out by the Pipeline and Hazardous Materials Safety Administration, U.S. EPA and U.S. Coast Guard, respectively.

The 1996 rules for oil-by-rail emergency response plans were crafted by the Research and Special Programs Administration, the precursor to PHMSA.

The agency said then that “on the basis of available information, no rail carrier is transporting oil in a quantity greater than 42,000 gallons in tank cars.”

NTSB has since questioned why the benchmark for comprehensive plans exists if it never actually applies. Officials at the Department of Transportation have until tomorrow to respond to NTSB’s criticisms.

“By limiting the comprehensive planning threshold for a single tank size that is greater than any currently in use, spill-planning regulations do not take into account the potential of a derailment of large numbers of 30,000-gallon tank cars, such as in Lac-Mégantic where 60 tank cars together released about 1.6 million gallons of crude oil,” NTSB’s Hersman wrote in her letter to PHMSA, also part of DOT.

In the wake of the Lac-Mégantic derailment, PHMSA has also faced pressure to update decades-old crude tank car rules. Critics say the outdated federal tank car standards and the FRA’s lack of oil spill emergency planning oversight point to the difficulty of keeping pace with the fast-growing crude-by-rail business.

The FRA and the railroad industry cite improving safety statistics, noting that more than 99.9 percent of all hazardous materials shipments reach their destination safely.

But despite declining accident rates over the past decade, regulatory consultant and attorney Paul Blackburn said, “citizens need to be concerned about … what happens over time.”

“After a big event like the Lac-Mégantic disaster, you’d expect the industry to be more cautious,” he said of recent voluntary safety measures. But “as these events fade from memory, there’s nothing to stop the industry from backing off on its commitment to improve spill response” barring federal action.

Reporter Mike Soraghan contributed.