Category Archives: Flash point

Bakken Crude, Crude By Rail, Diluted bitumen (Dilbit), Emergency Readiness & Response, Evacuation, Fire, First responder training, Flash point, Funding for emergency response, Let it burn, Spill, Tar sands crude

Templeton California retired fire chief: ‘Do not understate risk of oil trains’

Repost from the San Luis Obispo Tribune

Retired Templeton fire chief: Do not understate risk of oil trains

HIGHLIGHTS
• Despite training, emergency responders may not be able to prevent hundreds of fatalities in a derailment
• Highly flammable Canadian crude more dangerous than California crude
• Project should be denied if safety requirements can’t be enforced

By Greg O’Sullivan, October 23, 2015

Columnist John Peschong in his Aug. 23 column “Local responders are up to task” describes the extensive training and dedication of our emergency responders. This (in his opinion) means “emergency medical technicians and fire crews stand ready to protect us from any disaster,” including an oil train derailment and fire.

Greg O’Sullivan
Greg O’Sullivan, Retired Templeton Fire Chief

Having retired from the fire service after 38 years in the profession, as well as being a qualified hazmat technician and hazmat incident commander, I feel I can speak with greater authority about the ability of local responders to respond to an oil train derailment involving a fire and/or spill.

Mr. Peschong is correct when he states that many hours and dollars have been spent to train our emergency responders and they are capable of mitigating most emergencies. What he doesn’t explain is that an oil train derailment involving multicar fires in a highly populated area could result in hundreds of deaths, despite herculean efforts of first responders. For the incident commander of a hazmat incident, the team’s first responsibility is the safety of the public and our responders. In the case of a multiple car derailment involving fire, evacuation would be the highest priority.

If a life hazard exists, efforts focus on fire suppression to protect rescue operations. The area is isolated, and mutual aid as well as other authorities are notified to assist in the emergency. If evacuation has been successful and no further life hazard exists, then, and only then, could tactical decisions be made concerning whether or not fire suppression should be attempted, or whether the fire should be allowed to burn. It should be noted the closest Type 1 or 2 hazmat team is in Santa Barbara County.

Phillips 66 recently delivered beautifully designed surveys to some area residents expounding the virtues of its oil train project. But nowhere does it explain that approval of the project means five oil trains per week coming through San Luis Obispo County, each train pulling 80 tank cars filled with highly flammable Canadian crude oil. (That would be 500 million gallons per year.)

Al Fonzi in his Oct. 9 Viewpoint “Fear campaign against Phillips” declares that the tar sands crude oil (dilbit) Phillips 66 wants to transport from Canada is no more dangerous than the California crude from San Ardo that has been transported through the county by train for several decades. Mr. Fonzi bases this claim on the fact that the Canadian crude and San Ardo crude have similar vapor pressures.

Vapor pressure is only one measure of the hazard of a liquid. Fire professionals are far more familiar with flash point as the main determinant of flammability of a liquid. The flash point of California crude, like that found in San Ardo, ranges 199 to 232 degrees Fahrenheit (MSDS Product 94-0007-02). In contrast, the flashpoint of Canadian crude is reported to be minus 30 degrees (MSDS Heavy Crude/Diluent mix), comparable to gasoline at minus 42 degrees, both of which are considered highly flammable.

An oil train derailment involving multicar fires in a highly populated area could result in hundreds of deaths, despite herculean efforts of first responders.

Suppose a derailment involves only a spill. What would a single car rupture spilling 30,000 gallons of oil in the Salinas River do to the water supply of Atascadero, Templeton and Paso Robles? The train tracks parallel the Salinas. Mr. Fonzi says opponents of the oil trains are running a “cynical campaign to terrorize the public.”

It is unfair and inaccurate to label the many organizations and individuals who oppose the Phillips 66 oil train project as uninformed, fearful citizens. Opponents of the oil train project include such well-respected bodies as the League of Women Voters, National Education Association and 40 public bodies including city councils, school boards, fire chiefs’ organizations and elected officials, as well as the editorial board of The Tribune.

The final Environmental Impact Report is nearing completion, which will bring the project before the Planning Commission. Because of the serious local and regional safety issues of the project, I agree with and support the League of Women Voters that the Planning Commission and Board of Supervisors must “insist upon full and enforceable mitigations” for all risks, and that if these safety requirements cannot be enforced by the county, the project should be denied.

As a retired fire service professional, I believe protecting the safety of communities along the rail corridor outweighs any perceived benefit of the project. Don’t be misled by PR firms (similar to the one John Peschong represents) who are paid to spin the topic for Phillips 66. Please take the time to get the facts for yourself.

Greg O’Sullivan spent 38 years in the fire service, including 12 years as Templeton fire chief. After retiring, he served four years on the Board of Directors of the Templeton Community Services District.
Bakken Crude, Blast zone, Bridge safety, Cleanup funding, CPC-1232, Derailment, DOT-111, Emergency Readiness & Response, Explosion, Fire, Flash point, Foam, Fracking, Let it burn, Massive increase in crude-by-rail, Oil spill, Rail crossings, Rail inspection, Risk Assessment, Tar sands crude, Volatility

Buffalo’s Bomb Trains

Repost from ArtVoice, Buffalo, NY
[Editor: Professor Niman has written a thorough examination of crude-by-rail issues.  The local (Buffalo NY) perspective is no drawback.  This is an excellent reference article no matter where you are.  For example, if/when Benicia approves a permit for Valero’s proposed Crude By Rail project, everyone uprail from here can expect to be the new Buffalo.  – RS]

Buffalo’s Bomb Trains

By Michael I. Niman, February 26, 2015
With one third of Buffalo’s population living in a disaster evacuation zone, the local media’s silence is deafening.

They span over a mile long containing up to 140 tank cars and as much as 4.5 million gallons of some of the nastiest forms of crude oil on earth, pumped from “extreme” extraction operations in North America’s new oil boomtowns. They cross rivers and transverse open plains, wilderness forest and some of the most densely populated urban areas in the country. Occasionally, with alarmingly increasing frequency, they careen off into rivers, catch fire and explode, or both. When spilled in water, their heavy oil exterminates river ecosystems. When they blow up, they release the fires of hell, with one oil train accident in 2013 wiping out most of the town of Lac-Mégantic, Quebec, killing 47 people and gutting its downtown. That’s when folks started referring to these explosive steel snakes as “Bomb Trains.”

This is one of the dark sides of North America’s fossil energy boom—the backstory on cheap fuel. The uptick in oil production comes from using extreme means to recklessly drill oil, using carbon-intensive methods like fracking to extract environmentally dangerous low grade oils such as Bakken crude from Montana and North Dakota. This oil, pumped from the dolomite layer of the Bakken geological formation, which also underlies portions of the Canadian provinces of Saskatchewan and Manitoba, is more volatile than conventional oils, with a lower flashpoint for explosion. When rail cars started to blow in Lac-Mégantic, The National Post reported a blast radius of over one half mile.

The United States National Transportation Safety Board estimates that about 400,000 barrels a day of this oil make the trip to Atlantic Coast refineries, with 20 to 25 percent moving through the port of Albany. Much of this Albany-bound oil moves across New York utilizing rail lines passing though the hearts of Buffalo, Rochester, Syracuse and Utica. Oil from Canada crosses the Niagara river, entering the US both in Niagara Falls, and via Buffalo’s 142 year old International Railroad Bridge, as well as taking a northern route, dropping down from Quebec on tracks passing through the Adirondack Park, including about 100 miles of Lake Champlain watershed shoreline. Non Albany-bound oil, such as some shipments from Buford, North Dakota to Houston, Texas, also take an unlikely route through Buffalo.

Though much of this oil winds up moving through New York State, federal law limits the state’s authority to regulate it. While crude oil can be stabilized to make it less volatile in transit, whether or not it receives such treatment is up to the discretion of regulators in the state that produces it—not necessarily the states through whose cities it will roll. Most of the explosive Bakken crude coming our way originates in North Dakota, where the energy industry all but owns the legislature, fertilizing the state’s anti-regulatory zeitgeist with a healthy dose of cash. The end result is, whatever passes for a state government in North Dakota fails to meet even Texas’s modest safety standards for anti-explosive fuel stabilization.

The Association of American Railroads reports that, thanks to the Bakken and Tar Sands oil booms, the amount of oil moving across the country by train has increased 45 fold (4,500 percent) from 2008 through 2013, with the volume continuing to increase through 2014 and 2015. As a result, more oil spilled from oil trains in the U.S. in 2013 than in the preceding 37 years. The number of accidents increased in 2014, and seems to be steadily increasing this year, with oil trains derailing and blowing up last week in West Virginia and northern Ontario. The Associated Press reports that the U.S. Department of Transportation now predicts an average of ten derailment accidents a year involving crude oil or ethanol tank cars over the next twenty years, “causing more than $4 billion in damage and possibly killing hundreds of people if an accident happens in a densely populated part of the U.S.” It’s no longer a matter of “if” there will a catastrophic oil train derailment.

Both the New York State Office of Fire Prevention and Control, and the United States Department of Transportation recommend evacuating a one half mile perimeter around accidents involving railroad tanker cars carrying flammable liquids. Karen Edelstein, a researcher and the New York Program Director for the FracTracker Alliance, mapped oil train routes across the state, adding overlays for this evacuation zone, and for schools and hospitals. Her data shows that statewide, there are 502 public schools situated within potential evacuation zones. In Buffalo, about one third of the population live within one half mile of these bomb train routes, and 27 public schools and eight private schools lie within potential evacuation perimeters as well. This includes PS 42, which serves students with disabilities, and is located adjacent to the track. Sister’s Hospital and the Buffalo Zoo are well within this perimeter, which skirts the Buffalo State and Erie County Medical Center campuses. If we freak out when it snows, how well are we going to handle what appear to be atomic fireballs, should one of these trains blow up?

While the profits from this oil boom have been privatized, much of the cost associated with reckless extraction have been externalized, meaning dumped on the public. Aside from the obvious environmental costs that we and future generation will have to bear, are the less visible emergency preparation costs that every school, hospital and municipality within a half mile of bomb train routes must now cover. In Buffalo, this means 35 schools need to work with local emergency services providers to develop plans to quickly evacuate students not just from buildings, but from neighborhoods, all with a possible backdrop of explosions, sirens and billowing smoke.

While it’s not statistically likely that a train will explode in Buffalo or any other specific place, it is a certainty that trains will keep exploding with increasing frequency across the U.S. and Canada. This means that cash strapped municipalities across the continent will have to develop plans to address a catastrophe we know for certain will befall some of our communities.

Addressing this risk involves not just planning to respond to it, and maintaining an emergency response network capable of responding, but also working to prevent such a catastrophe. A report from the Cornell University Community and Regional Development Institute points out that this involves a multitude of responsibilities, such as monitoring surface rail crossings to prevent vehicle train collisions that can lead to a derailment. Such responsibility, the report notes, usually falls to local police forces that often lack the personnel to do this. Likewise, federal regulators lack the personnel to inspect the nation’s rail infrastructure, and state Departments of Transportation lack the resources to adequately inspect bridges crossing railroad tracks. All of these costs fall not on the oil or railroad industries, but on government agencies, with much of this work not being done due to budget constraints.

What little planning there is to deal with an oil train explosion is alarming to read. A three car fire requires, according to the New York State Office of Fire Prevention and Control , 80,000 gallons of water for laying down a fire retardant foam blanket and cooling adjacent rail cars. Hence, the state recommends, if there is “NO life hazard and more than 3 tank cars are involved in fire OFPC recommends LETTING THE FIRE BURN unless the foam and water supply required to control is available” [sic.]. The wording here is ominous, with the availability of the required foam and water not being the default expectation, but instead, simply a possibility. This language is there for a reason, however. The Auburn Citizen, in central New York, quotes Cayuga County Emergency Management Office Director Brian Dahl, who, in response to a question about his county’s ability to respond to an oil train fire, unequivocally states, “The amount of foam and water you would need, there’s just not enough in central New York.”

While oddly inferring that maybe you should put the fire out if you have adequate foam and water, even if there is no “life hazard,” the state’s instructions don’t mention what to do if there is a life hazard, but no foam or water. Also troubling is their inference that if more than three cars are on fire you should just give up. Last week’s fires in Ontario and West Virginia saw seven and fourteen cars ablaze respectively, with each fire burning for over 24 hours. In all caps, the state’s instructions warn responders,

“All resources must be available prior to beginning suppression.”

It doesn’t give any suggestions as to what to do if you can’t move the water to the fire, or have the foam necessary to smother a dragon. None of the suggested responses are tolerable should an oil train explode in an urban environment.

See FracTracker’s map of Buffalo’s evacuation zone: tinyurl.com/NYS-derailment-risks.

Dr. Michael I. Niman is a professor of journalism and media studies at SUNY Buffalo State. His previous columns are at artvoice.com, archived at www.mediastudy.com, and available globally through syndication.
CPC-1232, Crude By Rail, Derailment, Diluted bitumen (Dilbit), DOT-111, DOT-117, Fire, Flash point, Tar sands crude

RAILWAY AGE: Why tar sands train became a fireball – bitumen isn’t necessarily safer than Bakken

Repost from Railway Age
[Editor: Significant quote: “This blend of bitumen and petroleum-based diluents, known as “dilbit,” has a low flash point. Thus, the widespread belief that bitumen from Alberta’s northern oil sands is far safer to transport by rail than Bakken crude is, for all intents and purposes, dead wrong. This may be disruptive news for bitumen shippers, carriers, and regulators.”  – RS]

Why bitumen isn’t necessarily safer than Bakken

By  David Thomas, Contributing Editor, February 23, 2015 
Feb. 14, 2015 CN oil train derailment near Gogama, Ontario
Feb. 14, 2015 CN oil train derailment near Gogama, Ontario. CBC News/Dillon Daveikis

The chain reaction fireballs that attended the Feb. 16, 2015 derailment of a CSX unit oil train in populated West Virginia probably blinded observers to the significance of the concurrent derailment and explosions of a CN oil train in a remote and uninhabited area of northern Ontario. Most reports treated the two events as equals, given that both trains consisted of recently manufactured CPC-1232 tank cars loaded with crude oil.

CN’s Ontario conflagration is the more disturbing of the two mishaps: The railroad reported that its train was not carrying the extra-light Bakken crude that, in a series of high-energy derailments since 2013, has proved to be explosive. To the contrary, the CN train was laden with bitumen, the extra-heavy tarry substance extracted from Alberta’s oil sands. Bitumen, in its natural highly viscous form, is considered to be essentially inflammable by petrochemical experts and is rarely considered in safety evaluations of crude by rail.

So why did the bitumen ignite and explode in Ontario’s -40ºC (-40ºF) weather? The reason, based on research consulted by Railway Age, is that the diluent added to make bitumen flow into and out of tank cars makes the blended lading quite volatile.

This blend of bitumen and petroleum-based diluents, known as “dilbit,” has a low flash point. Thus, the widespread belief that bitumen from Alberta’s northern oil sands is far safer to transport by rail than Bakken crude is, for all intents and purposes, dead wrong. This may be disruptive news for bitumen shippers, carriers, and regulators.

The hope for Bakken crude is that it can be treated to remove benzene and other “light end” substances before loading, rendering it mildly flammable instead of highly explosive. The same is not true for dilbit, because the highly volatile diluents are added to the crude to make it less viscous. A safer procedure is to heat bitumen at origin before loading into a tank car and again at destination, prior to unloading. Some tank cars are equipped with internal steam coils for this purpose and are used in crude oil service, but a requirement for such heating elements is not included in the specifications proposed for a future DOT-117 tank car to replace both the DOT-111 and CPC-1232 cars now in CBR service.

According to “Properties of Dilbit and Conventional Crude Oils,” a February 2014 report by the Alberta Innovates consortium of industry, government, and university researchers, “[T]he flash point of fresh dilbit is initially lower than other oil types and is comparable to a diluent.” It says that dilbit will ignite upon exposure to an ignition source at -35ºC, compared to -9ºC for conventional light oil. The flash point of raw diluent is -35ºC or less. The flash point of undiluted bitumen is +151ºC, well above the +60ºC flammability threshold specified in current hazardous materials classification regulations.

The reason for the low flash point of dilbit is that ignitability is determined by a blend’s most volatile components, in this case, the diluent itself: “[T]he flash point is determined by the lowest-boil-point components (volatiles). Consequently, the flash point of the dilbit is governed by the 20%-30% volume diluent component . . . .”

The study defines flash point as “the temperature to which the fuel must be heated in order to produce an adequate fuel/air concentration to be ignited when exposed to an open flame. The flash point of the crude oil is used as an index of fire hazard in North America.”

Thus, flash point is the critical factor in determining whether a tank car breach will lead to its contents burning or exploding upon exposure to the pyrotechnics of a high-energy derailment.

Canada’s Transportation Safety Board can be expected to analyze the dilbit lading of CN’s Ontario accident, as it did the Bakken crude that exploded at Lac-Mégantic in 2013. TSB reported then that Bakken crude is more volatile than other varieties. Should TSB conclude that dilbit has a volatility similar to Bakken crude, as the Alberta research suggests, the hazmat classification of crude oil could be in question.